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Isochoric ideality in jammed random packings of non-spherical granular matter

机译:堵塞随机填料或非球形颗粒物质中的等容理想

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摘要

Randomly packed particles in granular matter, ubiquitous in nature and industry, usually defy simple predictions for the optimal amorphous packing density because jammed granules are strongly correlated. While mixing different granular shapes seems to be a further complication, we discovered in simulations that binary rod– sphere mixtures harbor a surprisingly simple dependence of packing volume fraction on mixture composition. This isochoric ideality covers the entire composition range and is experimentally validated by mixtures of sphero-cylindrical TicTac sweets and spherical beads: their joint random packing volume is indeed independent of the segregation state. Isochoric ideality occurs in a rod–shape range that includes the unique aspect ratio, which universally maximizes rod–sphere packing densities and suggests a novel amorphous analog of a plastic crystal, namely rod–sphere mixtures with completely uncorrelated particle orientations.
机译:在自然界和工业界普遍存在的颗粒状物质中的无规堆积颗粒通常会妨碍对最佳无定形堆积密度的简单预测,因为被堵塞的颗粒紧密相关。尽管混合不同的颗粒形状似乎是进一步的复杂化,但我们在模拟中发现,二元棒-球混合物具有令人惊讶的包装体积分数对混合物组成的简单依赖关系。这种等容的理想状态涵盖了整个成分范围,并通过球形TicTac糖和球形小珠的混合物进行了实验验证:它们的联合无规包装量确实与分离状态无关。等时线理想状态发生在包括独特长宽比的棒形范围内,该宽高比普遍使棒-球的堆积密度最大化,并提出了一种新颖的塑料晶体无定形类似物,即具有完全不相关的粒子取向的棒-球混合物。

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